西秦岭八卦庙金矿床原位S-Pb同位素组成对成矿物质来源和成矿过程的指示意义
Received:March 28, 2022  Revised:February 10, 2023  点此下载全文
引用本文:XU YiFan,HE WenBin,AN Fang,CAI GuangYao.2023.In situ S-Pb isotopes study of Baguamiao gold deposit, western Qinling: Constraints on its ore-forming material sources and metallogenic process[J].Mineral Deposits,42(4):773~790
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Author NameAffiliationE-mail
XU YiFan State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi'an 710069, Shaanxi, China  
HE WenBin State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi'an 710069, Shaanxi, China  
AN Fang State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi'an 710069, Shaanxi, China anfang_china@163.com 
CAI GuangYao Longshou Mine, Jinchuan Group Co., Ltd., Jinchang 737100, Gansu, China  
基金项目:本文得到国家级大学生创新创业训练计划项目(编号:202110697096)、国家自然科学基金项目(编号:42130102)和西北大学地质学系科研基金项目的联合资助
中文摘要:八卦庙金矿床位于西秦岭造山带凤太多金属矿田北部,已探明金储量约106 t(平均金品位1.56 g/t),属于特大型金矿。金矿体受脆韧性剪切带控制,总体走向NWW,倾向北,赋矿地层为上泥盆统星红铺组下段。文章在成矿期次研究基础上,采用硫化物原位S-Pb同位素分析方法,对八卦庙金矿成矿过程和成矿物质来源进行了约束。基于详细的野外观察和矿相学研究,矿区识别出了2个金成矿期:顺层磁黄铁矿-石英成矿期和NE向黄铁矿-石英成矿期。顺层磁黄铁矿-石英成矿期可划分为自形黄铁矿-石英(Ⅰ)、磁黄铁矿-自然金-铁白云石(Ⅱ)、白云母-绿泥石-绿帘石-石英(Ⅲ)3个阶段;NE向黄铁矿-石英成矿期由自形磁黄铁矿-黄铁矿-粗粒石英(Ⅳ)、他形黄铁矿-细粒石英(Ⅴ)、他形磁黄铁矿-自然金-铁白云石(Ⅵ)和石英-黑云母(Ⅶ)4个阶段构成。顺层磁黄铁矿-石英成矿期硫化物的δ34S值集中在1.60‰~5.89‰和14.07‰~16.87‰两个区间;NE向黄铁矿-石英成矿期硫化物的δ34S值也集中在2.77‰~5.52‰和9.11‰~15.9‰两个区间,通过与围岩和区内岩浆岩对比,笔者认为2个成矿期成矿热液中硫的来源和演化具有相似之处,初始流体中的硫既有围岩硫的贡献,也有岩浆硫的加入,随着成矿作用和水-岩相互作用的进行,成矿流体中围岩硫的比例逐渐升高。顺层成矿期硫化物具有混合铅的铅同位素特征(206Pb/204Pb=18.041~18.436,207Pb/204Pb=15.364~15.724,208Pb/204Pb=38.138~38.754),指示区内中酸性岩浆和赋矿地层来源铅的混合。NE向成矿期硫化物的铅同位素(206Pb/204Pb=18.393~18.400,207Pb/204Pb=15.639~15.687,208Pb/204Pb=38.648~38.917)略低于围岩硫化物,指示成矿流体中的铅主要来源于地层,但有少量岩浆铅的混入。
中文关键词:地球化学  成矿期次  原位S-Pb同位素  成矿物质来源  成矿过程  八卦庙金矿
 
In situ S-Pb isotopes study of Baguamiao gold deposit, western Qinling: Constraints on its ore-forming material sources and metallogenic process
Abstract:The Baguamiao gold deposit is in the northern part of Fengtai metal ore-concentrating district, West Qinling orogenic belt, with gold reserves of about 106 t@1.56 g/t. It is controlled by a brittle-ductile shear zone striking NWW, and hosted in the lower section of Upper Devonian Xinghongpu Formation. Its mineralization processes, and the sources of ore-forming materials were discussed by in situ S-Pb isotope analysis of sulfides in this study. Two ore-forming periods including strata-bounded pyrrhotite-quartz vein and NE-oriented pyrite-quartz vein periods were identified based on detailed field observations. The former can be divided into three stages:euhedral pyrite-quartz stage (Ⅰ), pyrrhotite-native gold-ankerite stage (Ⅱ), and biotite-chlorite-epidote-quartz stage (Ⅲ). The later includes four stages:euhedral pyrrhotite-pyrite-coarse-grained quartz stage (Ⅳ), anhedral pyrite-fine-grained quartz stage (Ⅴ), anhedral pyrrhotite-native gold-ankerite stage (Ⅵ), and quartz-biotite stage (Ⅶ). In situ S isotope results show that the δ34S values of sulfide in strata-bounded pyrrhotite-quartz veins cluster in two intervals of 1.60‰~5.89‰ and 14.07‰~16.87‰; The δ34S values of sulfide in the NE-oriented veins are also concentrated in 2.77‰~5.52‰ and 9.11‰~15.90‰. By comparison with the δ34S values of the wall-rocks and granitoid intrusions in the area, we figured that the initial sulfurs of the two periods ore-forming fluids are originated from both wall rock and contemporaneous magmatism, and the proportion of wall rock sulfur gradually increases with time. The lead isotopes of the sulfide in strata-bounded veins indicate that the lead was mainly from contemporaneous granitoid magmatism and wall-rocks(206Pb/204Pb=18.041~18.43, 207Pb/204Pb=15.364~15.724, 208Pb/204Pb=38.138~38.754), meanwhile, those of sulfides in the NE-oriented veins are very close to sulfides in the wall rocks(206Pb/204Pb=18.393~18.400, 207Pb/204Pb=15.639~15.687, 208Pb/204Pb=38.648~38.917), indicating that the lead mainly comes from the wall-rocks, with small contributions of magmatism.
keywords:geochemistry  paragenesis  in situ S-Pb isotope  source of ore-forming material  ore-forming history  Baguamiao gold deposit
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