厄立特里亚Koka金矿床成矿流体特征及其地质意义
Received:July 04, 2018  Revised:September 03, 2018  点此下载全文
引用本文:ZHAO Kai,YAO HuaZhou,WANG JianXiong,XIANG WenShuai,Ghebsha Fitwi Ghebretnsae.2018.Characteristics of ore-forming fluids of Koka gold deposit in Eritrea and their geological significances[J].Mineral Deposits,37(6):1337~1348
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Author NameAffiliation
ZHAO Kai Wuhan Center, China Geological Survey, Wuhan 430205, Hubei, China 
YAO HuaZhou Wuhan Center, China Geological Survey, Wuhan 430205, Hubei, China 
WANG JianXiong Wuhan Center, China Geological Survey, Wuhan 430205, Hubei, China 
XIANG WenShuai Wuhan Center, China Geological Survey, Wuhan 430205, Hubei, China 
Ghebsha Fitwi Ghebretnsae College of Silk Road, China University of Geosciences, Wuhan 430074, Hubei, China 
基金项目:中国地质调查局项目“埃及及邻区矿产资源潜力评价”(编号:DD20160109)项目资助
中文摘要:厄立特里亚Koka金矿床产于努比亚地盾新元古代浅变质岩系中,矿体主要赋存于Koka微晶花岗岩内,受剪切构造控制,是在该国发现的大型造山型金矿床。矿床含金石英脉中石英中赋存的原生流体包裹体分为富CO2包裹体、CO2-H2O包裹体和H2O包裹体共3种类型,以大量发育富CO2包裹体与CO2-H2O包裹体为特征。成矿流体具有富CO2、中低温(210~360℃)、中低盐度(w(NaCleq)=2.24%~8.51%)的特征。流体中阳离子主要为Na+与少量K+,阴离子为Cl-与少量SO42-,气相成分主要为CO2与H2O,基本不含其他气体组分,流体属于NaCl-H2O-CO2体系。成矿流体密度变化范围较大(0.597~0.969 g/cm3),其中高密度的富CO2包裹体捕获的最小P-T条件为260~360℃、100~270 MPa,形成于区域变质作用时期。成矿流体的δDV-SMOW范围为-57‰~-50.1‰,δ18O范围为1.4‰~3.2‰,表明Koka金矿床成矿流体主要来源于变质热液,并伴有大气降水的混入。成矿流体中CO2-H2O包裹体气相分数变化范围很大(15%~80%),与之共生的H2O包裹体具有相似的盐度以及较低的均一温度,表明初始的CO2-H2O型流体发生了不混溶作用,导致相分离,产生的大量富CO2流体,并使金大量沉淀。
中文关键词:地球化学  成矿流体  流体包裹体  不混溶  Koka金矿  厄立特里亚
 
Characteristics of ore-forming fluids of Koka gold deposit in Eritrea and their geological significances
Abstract:Located in the metamorphic strata of the Nubian Shield, the Koka gold deposit is a large orogenic gold deposit in Eritrea. The orebody hosts in the Koka aplitic granite, controlled by shear structure. The primary fluid inclusions in gold-bearing quartz veins can be divided into three types, i.e., extremely CO2-rich inclusions, CO2-H2O inclusions and H2O inclusions, with CO2-rich inclusions and CO2-H2O inclusions being dominant. The oreforming fluid is characterized by rich CO2, medium-low temperature (210~360℃) and low salinity (w(NaCleq)=2.24%~8.51%). In the liquid phase components, the cations mainly include Na+ and a little K+, the anions contain Cl- and a little SO42-, the gaseous content of the fluid inclusion is primarily CO2 and secondly H2O, almost without any other gaseous content, and the fluids belong to NaCl-H2O-CO2 system. The density of ore-forming fluid has a large variation (0.597~0.969 g/cm3), and the trapping P-T conditions of CO2-rich inclusions characterized by high density can be estimated to be 260~360℃ and 100~270 MPa, usually formed in regional metamorphism period. δDV-SMOW of the fluid is between -57‰ and -50.1‰, whereas δ18OH2O of the fluid is between 1.4‰ and 3.2‰, which suggests that the source of the ore-forming fluid for Koka gold deposit came mainly from metamorphic water mixed with meteoric water. The filling degree of CO2-H2O inclusions has a large variation (15%~80%), and symbiotic H2O inclusions have similar salinities and lower uniformity temperature, indicating that the original CO2-H2O fluid experienced fluid immiscibility, which resulted in the phase separation that formed a mass of CO2-rich fluid and caused gold precipitation.
keywords:geochemistry  ore-forming fluid  fluid inclusion  immiscibility  Koka gold deposit  Eritrea
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