内蒙古红花尔基白钨矿矿床流体包裹体研究
Received:December 31, 2014  Revised:July 30, 2015  点此下载全文
引用本文:GUO ZhiJun,LI JinWen,HUANG MengHui,GUO WanJun,DONG XuZhou,TIAN Jing,YANG YunCheng,SHE HongQuan,XIANG AnPing,KANG YongJian.2016.Characteristics of ore-forming fluid in Honghuaerji scheelite deposit, Inner M ongolia[J].Mineral Deposits,35(1):1~17
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Author NameAffiliationE-mail
GUO ZhiJun State Key Laboratory of Mineral Processing Science and Technology, Beijing Ge neral Research Institute of Mining and Metallurgy, Beijing 102628, China ghn-07@163.com 
LI JinWen MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resou rces, Chinese Academy of Geological Sciences, Beijing 100037, China lijinwen958@sohu.com 
HUANG MengHui Inner Mon golia Institute of Geology and Mineral Exploration, Hohhot 010011, Inner Mongolia, China  
GUO WanJun Inner Mongolia Sixth Geological Mineral Exploration Institute , Hailar 021000, Inner Mongolia, China  
DONG XuZhou School of Earth Science and Mineral Resources, China University of Geosciences, Beijing 100083, China  
TIAN Jing MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resou rces, Chinese Academy of Geological Sciences, Beijing 100037, China
School of Earth Science and Mineral Resources, China University of Geosciences, Beijing 100083, China 
 
YANG YunCheng MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resou rces, Chinese Academy of Geological Sciences, Beijing 100037, China  
SHE HongQuan MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resou rces, Chinese Academy of Geological Sciences, Beijing 100037, China  
XIANG AnPing MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resou rces, Chinese Academy of Geological Sciences, Beijing 100037, China  
KANG YongJian MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resou rces, Chinese Academy of Geological Sciences, Beijing 100037, China  
基金项目:本文得到科技部973 项目(编号: 2013CB428805)和中国地质调查局地质调查项目(编号 : 科[2013]01-042-003)联合资助
中文摘要:红花尔基白钨矿矿床为内蒙古大兴安岭中北段地区新发现的一处钨矿 规模接近 大型的W-Mo矿床。文章通过系统的岩相学、矿相学、流体包裹体和碳、氢、氧同位素研究, 表明红花尔基白钨矿矿床属岩浆期后热液充填-交代矿床,可划分为钾长石、钠长石阶段→ 白 钨矿-石英阶段→辉钼矿-石英阶段→铜、铁、铅、锌硫化物-石英阶段→碳酸盐-石英阶段5 个成矿阶段。矿床内的白钨矿、石英以及碳酸盐中的流体包裹体均以富液相气液两相水溶液 包裹体为主。白钨矿-石英阶段的均一温度范围为290~395℃,峰值为360~370℃,盐度 w(NaCleq)范围为088%~702%,峰值为2%~3%,结合包裹体激光拉曼分 析,得出与钨矿形成有 关 的 流体为中高温、低盐度的NaCl-H2O体系的结论。白钨矿和石英的H-O以及碳酸盐的C-H-O同 位素特征表明,成矿流体主要是岩浆水,并有少量大气降水的混合。成矿流体为岩浆结晶分 异作用形 成的富钨等成矿元素的热液。矿区花岗岩的云英岩化可能将钙萃取进入流体,参与白钨矿结 晶、沉淀。
中文关键词:地球化学  流体包裹体  白钨矿  碳氢氧同位素  红花尔基  内蒙古
 
Characteristics of ore-forming fluid in Honghuaerji scheelite deposit, Inner M ongolia
Abstract:The Honghuaerji scheelite deposit is a newly discovered large W-Mo deposit i n the middle and northern Da Hinggan Mountains, Inner Mongolia. Ore petrography, fluid inclusions and C-H-O isotopic compositions show that the Honghuaerji depo sit was formed by post-magmatic hydrothermal process, which can be divided into five ore-forming stages: potassic feldspar-albite stage, scheelite-quartz stage , molybdenite-quartz stage, Cu-Pb-Zn-Fe metal sulfides-quartz stage and carbonat e-quartz stage. The fluid inclusion types in scheelite, quartz and carbonate are mainly liquid-rich two-phase inclusions. The data show that the homogeneous tem peratures of fluid inclusions of the scheelite-quartz stage are 290~395℃, with the peak of 360~370℃, and the salinities are 088%~702%, with the peak of 2% ~ 3%. Combined with the Laser Raman analysis of the flui d inclusions, the authors have reached the conclusion that the scheelite-related fluids were of the medium-high temperature and low salinity NaCl-H2O fluid sy stem. An analysis of C-H-O isotope reveals that the hydrothermal fluids were mai nly of magmatic hydrothermal fluids, mixed with a little meteoric water. Studies indicate that the fluid related to tungsten mineralization might have been deri ved mainly from crystallization and differentiation of magma, and the Ca2+ was probably released from the plagioclase by greisenization.
keywords:geochemistry, fluid inclusion, scheelite, C-H-O isotope, Honghuaerji, Inner Mong olia
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