安徽铜陵矿集区海底喷流沉积体系的流体包裹体微量元素对比 |
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引用本文:.2004.Trace Elements in Fluid Inclusions of Submarine Exhalation-Sedimentation System in Tongling Metallogenic Province[J].Mineral Deposits,23(3):344~352 |
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基金项目:国土资源部专项研究计划(编号:20010103)之项目二“铜陵矿集区三维蚀变填图与流 体示踪研究” |
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中文摘要:铜陵矿集区与铜_金(多金属)矿床有关的热液活动主要有两大体系,即 与海西期海底喷流沉积有关的热液体系和与矽卡岩矿化有关的燕山期岩浆热液体系。查明这 两类热液体系的流体包裹体特征对区域找矿和矿床成因研究都有实际意义。在包裹体岩相学 研究基础上,应用ICP_MS技术和热爆提取方法,研究了新桥、冬瓜山、峙门口、铜官山、朝 山等矿床具代表性的热液石英中流体包裹体的微量元素、稀土元素特征。结果表明,两类热 液体系在流体包裹体特征上有较大的区别,在流体的微量元素和稀土元素特征方面也很不相 同。海底喷流沉积体系的热液石英中流体包裹体与岩浆热液体系的相比,稀土总量较高,LR EE/HREE比值较大,δEu不明显,且Mo/(W+Sn)比值较高,反映流体中成矿物质的深源特征; Ga/Tl、Rb/Cs大,Zr/Hf低,也不同于岩浆热液体系。 |
中文关键词:地球化学 海底喷流沉积 流体包裹体 ICP-MS 微量元素 |
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Trace Elements in Fluid Inclusions of Submarine Exhalation-Sedimentation System in Tongling Metallogenic Province |
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Abstract:Hydrothermal fluids related to copper_gold (polymetallic) deposits in Tongling M etallogenic province can be classified into two types, i.e., fluids associated w ith Hercynian submarine exhalation_sedimentation and those related to skarn alte ration during Yanshanian magmatic movement. Two systems are recognized on the ba sis of characteristics of fluid inclusions, especially those of trace elements a nd rare earth elements in fluid inclusions. With ICP_MS and heating_decrepitatio n techniques, the authors studied fluid inclusions in quartz samples from such d eposits as Xinqiao, Dongguashan, zhimenkou, Tongguanshan and Chaoshan so as to p robe into rare earth elements and other trace elements. The results show that fl uid inclusions in quartz of the submarine exhalation_sedimentation system have h igher ΣREE, larger LREE/HREE than those of the magmatic hydrothermal system. Th e Eu anomaly is not clear in the submarine exhalation_sedimentation system. The Mo/(W+Sn) ratios are relatively high, indicating a deep source of ore materials in the submarine exhalation_sedimentation system. High Ga/Tl, large Rb/Cs and lo w Zr/Hf are also different from the corresponding values of the magmatic hydroth ermal system. |
keywords:geochemistry, submarine exhalation_sedimentation, fluid inclusions, ICP_MS, trace elements |
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