中文摘要:流体包裹体研究表明,纳沃日金矿成矿脉体中流体包裹体类型有三种,富CH4、CH4-CO2-H2O和富H2O包裹体。初始成矿流体是富CH4热液,在主矿化阶段,另一来源的CO2 -H2O流体与CH4流体发生了不均匀混合,并且在石英一磁黄铁矿阶段最为强烈,造成不同矿化部位的x CH4变化极大,早期近于纯CH4流体被充分“稀释”,石英-黄铁矿阶段的XCH4显著减小,到成矿晚期只剩CO2 -H2O流体。正是由于不同性质流体的混合,造成热液的pH及f02的升高,流体中的金-硫络合物分解,金沉淀成矿。
Abstract:The Nevoria deposit, a banded iron formation-hosted gold deposit, occurs within the roof of amphibolite-facies greenstones in the Southern Cross belt, Yilgarn Block, Western Australia. The mineralizing veins include early quartz-pyrrhotite+ chalcopyrite veins and late quartz- pyrite veins. Three types of fluid inclusions, namely CH4-rich, CH4-CO2-H2O and H2O-rich ones, were found at Nevoria. Microthermometric data reveal that the initial auriferous fluids were CH4-dominant. Fluid mixing may have caused remarkable variations of CH4/CO2 ratios or XCH4 of CH4-CO2-H2O inclusions, particularly in mineralized quartz-pyrrhotite veins. The CH4-C02-H2O inclusions in quartz-pyrite vein set have an apparent trend of decreasing XCH4 and increasing molar volume.It can be inferred that, from the quartz-pyrrhotite stage to the quartz-pyrite stage, homogenization temperatures of CH4-CO2-H2O inclusions decreased, and CH4 contents ( XCH4) also decreased. The carbonic phase in the inclusions varies from CH4-dominant to CO2-dominant. Phase mixing, resulting in an increase in pH and toz, together with loss of reduced sulfur by mineral/fluid reactions and precipitation of sulfides, led to the breakdown of the gold-transporting complexes.
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范宏瑞,D I Groves,E J Mikuckj,N J McNaughton.2001.澳大利亚纳沃日金矿流体混合与金的成矿作用[J].矿床地质,20(1):37~43.2001.Fluid Mixing in the Generation of Nevoria Gold Mineralisation in the Southern Cross Greenstone Belt, Western Australia[J].Mineral Deposits20(1):37~43
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