矿床地质:2018,Vol.>>Issue(2):403-419

河南崤山金矿床流体包裹体及同位素特征
中国地质科学院矿产资源研究所 国土资源部成矿作用与资源评价重点实验室, 北京 100037,河南省地质矿产勘查开发局第一地质矿产调查院, 河南 洛阳 471000;河南省金银多金属成矿系列与深部预测重点实验室, 河南 洛阳 471000,万宝矿产有限公司, 北京 100053,河南省地质矿产勘查开发局第一地质矿产调查院, 河南 洛阳 471000;河南省金银多金属成矿系列与深部预测重点实验室, 河南 洛阳 471000,武警黄金第四支队, 辽宁 辽阳 111000,中国地质科学院矿产资源研究所 国土资源部成矿作用与资源评价重点实验室, 北京 100037,崤山黄金矿业有限公司, 河南 三门峡 472000
Fluid inclusions and isotopic characteristics of Xiaoshan gold deposit in Henan Province
LI TieGang,MENG XianFeng,WANG GuoRui,XIAO JianHui,WU Hao,FAN HaiYang,YUAN XiaoQi
(MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China;No.1 Institute of Geological and Mineral Resources Survey, Development of Geology and Mineral Resources of Henan Province, Luoyang 471000, Henan, China;Key Laboratory of Au-Ag-Polymetallic Deposit Series and Deep-seated Metallogenic Prognosis of Henan Province, Luoyang 471000, Henan, China;Wanbao Mining Co., Ltd., Beijing 100053, China;Fourth Detachment of Gold Headquarters, Chinese Armed Police Force, Liaoyang 111000, Liaoning, China;Xiaoshan Gold Mining Co., Ltd., Sanmenxia 472000, Henan, China)
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投稿时间:2017-10-20   修订日期:2018-02-08      网络发布日期:2018-04-25
中文摘要:崤山金矿床位于华北克拉通南缘的豫西地区,矿体大多呈脉状产于断裂带内。成矿期可以划分为3个阶段:①石英-黄铁矿阶段;②石英-多金属硫化物阶段;③石英-碳酸盐阶段。成矿期石英中发育气液两相水溶液包裹体(WL型)和H2O-CO2包裹体(C型)。石英-黄铁矿阶段发育WL型和C型包裹体,它们的均一温度为300~393℃,盐度w(NaCleq)为1.6%~11.0%,密度介于0.57~0.82 g/cm3;石英-多金属硫化物阶段亦发育WL型和C型包裹体,它们的均一温度为261~298℃,盐度w(NaCleq)为1.1%~11.8%,密度介于0.74~0.89 g/cm3;石英-碳酸盐阶段仅见WL型包裹体,其均一温度为193~258℃,盐度w(NaCleq)介于2.2%~12.7%,密度为0.87~0.97 g/cm3。成矿流体具有中高温、中低盐度、低密度等特征,属于H2O-NaCl±CO2体系。崤山金矿石英的δ18OH2O值介于0.7‰~4.5‰之间,δDV-SMOW值介于-47.8‰~-69.5‰之间。H-O同位素结果表明成矿流体主要来源于岩浆水。矿石硫化物的δ34SV-CDT值为0.7‰~3.9‰,206Pb/204Pb值为17.391~17.728,207Pb/204Pb值为15.420~15.577,207Pb/204Pb值为37.420~37.923。S-Pb同位素结果表明成矿物质主要来源于花岗质岩浆。崤山金矿为中温热液脉型金矿,流体相分离和温度的降低是导致矿质沉淀的主要机制。
Abstract:The Xiaoshan gold deposit is located on the southern margin of the North China craton in western Henan Province. Orebodies occur as veins in the fault zones. The ore-forming process can be divided into three stages:The early quartz-pyrite stage, the middle quartz-polymetallic sulfide stage, and the late quartz-carbonate stage. Two types of fluid inclusions (FIs) were distinguished in various quartz veins, i.e., liquid-rich (WL type) and H2O-CO2 (C-type) inclusions. The fluid inclusions in the quartz of the quartz-pyrite stage comprise WL-and C-type inclusions; their homogenization temperatures, salinities w(NaCleq), and densities vary from 300 to 393℃, 0.57% to 0.82%, and 1.6 to 11.0 g/cm3, respectively. The fluid inclusions in the quartz of the quartz-polymetallic sulfide stage consist of WL-and C-type inclusions; their homogenization temperatures, salinities w(NaCleq), and densities range from 261 to 298℃, 1.1% to 11.8%, and 0.74 to 0.89 g/cm3, respectively. There are only WL-type inclusions in the quartz of the quartz-carbonate stage; their homogenization temperatures, salinities w(NaCleq), and densities vary from 193 to 258℃, 2.2% to 12.7%, and 0.87 to 0.97 g/cm3, respectively. The ore-forming fluids of the Xiaoshan gold deposit are generally characterized by moderate-high temperature, moderate-low salinity, and low density, thus belonging to the H2O-NaCl±CO2 system. The δ18OH2O values calculated for ore-bearing quartz vary from 0.7‰ to 4.5‰, and the δDV-SMOW values from bulk extraction of fluid inclusion water vary from -47.8‰ to -69.5‰, suggesting that the ore-forming fluids consist dominantly of magmatic water. The δ34SV-CDT values range from 0.37‰ to 3.9‰. The 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios of the ore minerals are in the ranges of 17.391~17.728, 15.420~15.577, and 37.420~37.923, respectively. The data from the S and Pb isotopic systems indicate that the ore-forming materials came from the granitic magma. The Xiaoshan gold deposit is a mesothermal vein-type gold deposit. Fluid phase separation and temperature decrease seem to have been the dominant mechanism for the deposition of ore-forming materials.
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基金项目:中国地质调查局地质调查项目(编号:12120114035201)和中国地质调查局中国矿产地质与成矿规律综合集成和服务(矿产地质志)项目(编号:DD20160346)资助
引用文本:
李铁刚,孟宪锋,王国瑞,肖建辉,吴昊,范海洋,员晓琪.2018.河南崤山金矿床流体包裹体及同位素特征[J].矿床地质,37(2):403~419
LI TieGang,MENG XianFeng,WANG GuoRui,XIAO JianHui,WU Hao,FAN HaiYang,YUAN XiaoQi.2018.Fluid inclusions and isotopic characteristics of Xiaoshan gold deposit in Henan Province[J].Mineral Deposits37(2):403~419
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